Go to your local bookstore and buy a good book on (X)HTML and CSS. Master these two skills, then start worrying about more advanced things such as php, JavaScript, graphic design, etc.
Also, if you can afford it, consider investing in a WYSIWYG editor such as Dreamweaver or Microsoft Expression Web. I prefer Dreamweaver because of its autosuggest feature, but I'm sure Expression Web has something similar. Tools like this can help you learn quicker, but make sure you write your own code instead of dragging and dropping and having the editor write the code for you.